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This post provides a simple example of how we can use PowerShell ADSI to search users in Active Directory. You may wish to further optimise this by using LDAP filters.
$searcher=[adsisearcher]'(&(objectCategory=person)(objectClass=user))'
$searcher.PageSize = 200
$colProplist = "samaccountname"
foreach ($i in $colPropList) { $searcher.PropertiesToLoad.Add($i) | out-null }
$Users = $searcher.findall()
foreach ($user in $Users) {
write-host ($user.Properties).samaccountname
}